Contact 'buyer A' who should have received two items. Explain one item was sent in error and ask them to return it to you.
They won't be able to do this through Ebay/a return case because it's an item they didn't buy.
You will have to pay for the return. You can send them a payment via Paypal or direct to their bank or possibly send them a stamped, addressed postage bag/padded envelope etc. for them to use to send it back to you.
You are in the buyer's hands so be really apologetic and helpful in enabling them to send the item back.
Has 'buyer B' opened a case?
if they have you can refund them in full or ask them to wait for a few days while you try to get their item back.
"There are two ways to be fooled. One is to believe what isn't true; the other is to refuse to believe what is true.”
Søren Kierkegaard, Danish philosopher (1813 - 1855)