As the other poster has said, if you are concerned then for future transactions the immediate payment option for BIN's might be a way to go.
Other than that, open a unpaid dispute, if it's more than 2 days, or contact the buyer either via email or telephone. The last you can request if it isn't available. If the buyer has some history there may be reasons they haven' t paid;Contacting them first if possible, might be the best way to start with.