It depends on a few factors, all the info is here https://www.royalmail.com/windsor-framework
The last few items i have shipped to Northern Ireland have needed simple export forms to be filled in on the click and drop business website.
They required description of item, cost, weight, commodity code, country of manufacture, their EORI number if they are a business.
You might fall under C2C,
Parcels sent by a private individual in Great Britain to a private individual residing in Northern Ireland for personal use. Goods description, confirmation of goods categorisation by item (optional), weight (by item), value (by item).